International Chemical Safety Cards

sec-HEXYL ACETATE

ICSC: 1335

1,3-Dimethylbutyl acetate
Methylisoamyl acetate
Acetic acid, 1,3-dimethylbutyl ester
4-Methyl-2-pentanol, acetate
C₈H₁₆O₂ / CH₃COOCH(CH₃)CH₂CH(CH₃)₂
Molecular mass: 144.2

ICSC #    1335
CAS #     108-84-9
RTECS # SA7525000
UN #        1233

TYPES OF HAZARD/ EXPOSURE	ACUTE HAZARDS/ SYMPTOMS	PREVENTION	FIRST AID/ FIRE FIGHTING
FIRE	Flammable.	NO open flames, NO sparks, and NO smoking.	Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION	Above 45°C explosive vapour/air mixtures may be formed.	Above 45°C use a closed system, ventilation, and explosion-proof electrical equipment.	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE
•INHALATION	Cough. Sore throat.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest.
•SKIN	Redness.	Protective gloves.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
•EYES	Redness.	Safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
•INGESTION			Rinse mouth.

SPILLAGE DISPOSAL

STORAGE

PACKAGING & LABELLING

Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours).

Fireproof. Separated from strong oxidants.

R:
S:
UN Hazard Class: 3
UN Packing Group: 108-84-9 1335

SEE IMPORTANT INFORMATION ON BACK

ICSC: 1335

Prepared in the context of cooperation between the International Programme on Chemical Safety & the Commission of the European Communities (C) IPCS CEC 2001. No modifications to the International version have been made except to add the OSHA PELs, NIOSH RELs and NIOSH IDLH values.

International Chemical Safety Cards

sec-HEXYL ACETATE

ICSC: 1335

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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:

CHEMICAL DANGERS:
Reacts with strong oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: 50 ppm; 295 mg/m³ (as TWA) (ACGIH 1997).
MAK: 50 ppm; 300 mg/m³; I (1996)
OSHA PEL: TWA 50 ppm (300 mg/m³)
NIOSH REL: TWA 50 ppm (300 mg/m³)
NIOSH IDLH: 500 ppm

ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour.

INHALATION RISK:
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes the skin the respiratory tract Exposure at high levels may result in unconsciousness.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:

PHYSICAL
PROPERTIES

Boiling point: 146°C
Melting point: -64°C
Relative density (water = 1): 0.86
Solubility in water: none
Vapour pressure, kPa at 20°C: 0.4

Relative vapour density (air = 1): 5.0
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.01
Flash point: 45°C c.c.
Explosive limits, vol% in air: 0.9-5.7

ENVIRONMENTAL
DATA

N O T E S

Transport Emergency Card: TEC (R)-30G35
NFPA Code: H1; F2; R0;

ADDITIONAL INFORMATION

ICSC: 1335	sec-HEXYL ACETATE
(C) IPCS, CEC, 2001

IMPORTANT LEGAL NOTICE:

Neither NIOSH, the CEC or the IPCS nor any person acting on behalf of NIOSH, the CEC or the IPCS is responsible for the use which might be made of this information. This card contains the collective views of the IPCS Peer Review Committee and may not reflect in all cases all the detailed requirements included in national legislation on the subject. The user should verify compliance of the cards with the relevant legislation in the country of use. The only modifications made to produce the U.S. version is inclusion of the OSHA PELs, NIOSH RELs and NIOSH IDLH values.